STUDIES ON STEROIDAL PLANT-GROWTH REGULATOR .21. A STEREOSELECTIVE CONSTRUCTION OF BRASSINOSTEROID SIDE-CHAIN - A NEW PRACTICAL SYNTHESIS OF BRASSINOLIDE AND ITS ANALOGS

被引：33

作者：

ZHOU, WS ^{[1
]}

HUANG, LF ^{[1
]}

SUN, LQ ^{[1
]}

PAN, XF ^{[1
]}

机构：

[1] LANZHOU UNIV,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)93592-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The high stereoselectivity in osmium tetroxide catalyzed asymmetric dihydroxylation of DELTA-22(23)-methyl hyodeoxycholate has been achieved, and the utilizing of (22R, 23S)-22,23-dihydroxy methyl hyodeoxycholate as starting material for syntheses of brassinolide and its analogues is described.

引用

页码：6745 / 6748

页数：4

共 31 条

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