THEORETICAL-STUDY OF 1,3-DIPOLAR CYCLOADDITIONS - INFLUENCE OF AN ACTIVATED ALKENE SUBSTITUENT ON THE TRANSITION-STATES AND REGIOSELECTIVITY OF NITRONE ADDITION

被引：17

作者：

PASCAL, YL ^{[1
]}

CHANETRAY, J ^{[1
]}

VESSIERE, R ^{[1
]}

ZEROUAL, A ^{[1
]}

机构：

[1] UNIV CLERMONT FERRAND,CHIM ORGAN LAB 2,F-63177 CLERMONT FERRAND,FRANCE

来源：

TETRAHEDRON | 1992年 / 48卷 / 35期

关键词：

D O I：

10.1016/S0040-4020(01)88260-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The transition states of the 1,3-dipolar cycloaddition of nitrone CH2=N+H-O- upon various monosubstitued alkenes, with withdrawing and releasing substituents, were obtained from AM1 method. The synchronism and regioselectivity of the process were evaluated, in good agreement with experimental results.

引用

页码：7197 / 7208

页数：12

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