SUBPICOSECOND FLUORESCENCE STUDY OF THE LDS-751 DYE MOLECULE IN ETHANOL

被引:13
作者
HEBERT, P
BALDACCHINO, G
GUSTAVSSON, T
MIALOCQ, JC
机构
关键词
D O I
10.1016/0009-2614(93)85143-C
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A time-dependent fluorescence Stokes shift study of the LDS 751 (styryl 8) dye molecule in ethanol solution is presented. Fluorescence intensity curves were recorded with sub-picosecond time resolution at various wavelengths using the fluorescence upconversion method. From the experimental curves, time-resolved fluorescence spectra have been reconstructed, allowing the calculation of the spectral shift correlation function c(t) = [vBAR(t) -vBAR(infinity)]/[vBAR(0) -vBAR(infinity) ]. We find c(t) of LDS 751 in ethanol at room temperature to be well described by a monoexponential function with a 1/e time of 5 +/- 1 ps.
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页码:345 / 350
页数:6
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