ACTIVATION OF CHELATED CATECHOLATOIRON SPECIES FOR CATALYTIC OXYGENATION OF CATECHOLS BY CATECHOLDIOXYGENASE-MODEL IRON COMPLEXES

被引：14

作者：

FUNABIKI, T

ISHIKAWA, M

NAGAI, Y

YORITA, J

YOSHIDA, S

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 17期

关键词：

D O I：

10.1039/c39940001951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactivity of the isolated catecholatoiron complex with O-2 and the spectroscopic observation of the reversible catechoate ligand exchange reveal that a stable chelated catecholate species may be activated to be reactive with O-2 in the catalytic system.

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页码：1951 / 1952

页数：2

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