NUCLEAR MAGNETIC RESONANCE ANALYSES AND PARAMETERS FOR SOME MONOHALOSUBSTITUTED FLUOROBENZENES

被引:43
作者
LOEMKER, JE
READ, JM
GOLDSTEIN, JH
机构
[1] Department of Chemistry, Emory University, Atlanta
关键词
D O I
10.1021/j100849a033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The nmr spectra of a number of o-, m-, and p-halo-substituted fluorobenzenes have been recorded and precise values of the nmr parameters have been determined by analysis. The H-F couplings have been compared with the corresponding couplings in fluorobenzene and, in addition, correlations between the H-F couplings and substituent electronegativity have been observed. These substituent effects vary in direction and magnitude, depending on the relative positions around the ring.
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收藏
页码:991 / +
页数:1
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