AN X-RAY DIFFRACTION STUDY OF ZEOLITE COMPLEX M-DICHLOROBENZENE-NICKEL FAUJASITE

被引:25
作者
SIMPSON, HD
STEINFIN.H
机构
[1] Materials Science Laboratory, Department of Chemical Engineering, University of Texas at Austin, Austin
关键词
D O I
10.1021/ja01051a003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of the zeolite complex m-dichlorobenzene-nickel faujasite has been studied using single-crystal X-ray techniques. An analysis of the low-order data, using formulas for the average scattering of X-rays from species in various forms of uniform distribution, shows that the sorbed organic molecules form a liquid or near-liquid in the intracrystalline channels. The situation regarding the located nonframework species is similar to that for hydrated natural faujasite. © 1969, American Chemical Society. All rights reserved.
引用
收藏
页码:6225 / &
相关论文
共 14 条
[1]  
BAUR WH, 1964, AM MINERAL, V49, P697
[2]  
Bergerhoff G., 1958, NEUES JB MINER MONAT, P193
[3]   THE STRUCTURES OF SYNTHETIC MOLECULAR SIEVES [J].
BROUSSARD, L ;
SHOEMAKER, DP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (05) :1041-1051
[4]  
BURNHAM CW, 1963, IBM7097090 COMP PROG
[5]  
HAMILTON WC, 1965, NORELCO REPORTER, V12, P31
[6]  
HAMILTON WC, 1965, ACTA CRYST, V18, P5021
[7]  
JAMES RW, 1950, OPTICAL PRINCIPLES D, V2, pCH9
[8]  
MACK M, 1965, NORELCO REP, V12, P40
[9]   CRYSTAL STRUCTURE OF ZEOLITE NICKEL FAUJASITE [J].
OLSON, DH .
JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (13) :4366-+
[10]   CRYSTAL STRUCTURE OF CERIUM (3) EXCHANGED FAUJASITE [J].
OLSON, DH ;
KOKOTAIL.GT ;
CHARNELL, JF .
NATURE, 1967, 215 (5098) :270-&