OXEPINOBENZOFURANS - TRUE NATURE OF STERICALLY HINDERED BENZOXETES

被引：31

作者：

MEIER, H

SCHNEIDER, HP

RIEKER, A

HITCHCOCK, PB

机构：

[1] UNIV TUBINGEN,INST ORGAN CHEM,D-7400 TUBINGEN 1,FED REP GER

[2] UNIV SUSSEX,SCH MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1978年 / 17卷 / 02期

关键词：

D O I：

10.1002/anie.197801211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compounds hitherto regarded as benzoxetes 1 have proved to be oxepins 2. Structure 3 was ruled out by X‐ray structure analysis of 2, R1=tBu, R2R4Cl, R3OMe. This result appears particularly important with regard to oxidative coupling of phenols (biogenesis of phenolic natural products). (Figure Presented.) Copyright © 1978 by Verlag Chemie, GmbH, Germany

引用

页码：121 / 123

页数：3

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