PHENYLSELENYL HALIDES - EFFICIENT REAGENTS FOR THE SELECTIVE HALOGENATION AND NITRATION OF PORPHYRINS

被引：16

作者：

ALI, H ^{[1
]}

VANLIER, JE ^{[1
]}

机构：

[1] UNIV SHERBROOKE,FAC MED,MRC,RADIAT SCI GRP,SHERBROOKE J1H 5N4,QUEBEC,CANADA

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 38期

关键词：

D O I：

10.1016/S0040-4039(00)93415-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of OEPNi with PhSeCl or PhSeCl3, yields mono- through tetra-meso-chlorinated products. The reaction of PhSeCl3 with TPPNi likewise gives di- through poly-beta-chlorinated products. When PhSeBr or PhSeBr3 is used as the reagent, OEPNi gives brominated products with the loss of an ethyl group, while the TPPNi yields beta-brominated analogs. Nitration of OEPNi is accomplished using PhSeCl together with AgNO2.

引用

页码：5015 / 5018

页数：4

共 14 条

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