PLANTS FROM NEW-CALEDONIA .134. ALKALOIDS FROM ALSTONIA-UNDULATA

被引：19

作者：

PINCHON, TM ^{[1
]}

NUZILLARD, JM ^{[1
]}

RICHARD, B ^{[1
]}

MASSIOT, G ^{[1
]}

LEMENOLIVIER, L ^{[1
]}

SEVENET, T ^{[1
]}

机构：

[1] INST CHIM SUBST NAT,CNRS,F-91198 GIF SUR YVETTE,FRANCE

来源：

PHYTOCHEMISTRY | 1990年 / 29卷 / 10期

关键词：

Alstonia undulata; Apocynaceae; indole alkaloids; leaves; pericyclivine;

D O I：

10.1016/0031-9422(90)80211-X

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Six new alkaloids have been isolated and identified in the leaves ofAlstonia undulata from New Caledonia. They are 10-hydroxypericyclivine,N(1)-methyl-10-hydroxypericyclivine, 10-methoxypericyclivine,N(1)-methyl-10-methoxypericyclivine,N(1)-methyl 16-epipericyclivine and voachalotinal. The last two alkaloids are identical to hemisynthetic products derived from quebrachidine. Stereochemistry at C-16 ofN(1)-methyl 16-epipericyclivine has been proved by a chemical correlation. © 1990 Pergamon Press plc.

引用

页码：3341 / 3344

页数：4

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