SILICON CARBON UNSATURATED-COMPOUNDS .34. FORMATION OF BIS(TRIMETHYLSILYL)SILENES FROM ACYLTRIS(TRIMETHYLSILYL)SILANES VIA A PETERSON-TYPE REACTION

被引：54

作者：

OHSHITA, J ^{[1
]}

MASAOKA, Y ^{[1
]}

ISHIKAWA, M ^{[1
]}

机构：

[1] HIROSHIMA UNIV,FAC ENGN,DEPT APPL CHEM,HIROSHIMA 724,JAPAN

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 10期

关键词：

D O I：

10.1021/om00056a061

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of acetyltris(trimethylsilyl)silane with methyllithium at -80-degrees-C gave 1-isopropyl-2-(2-propenyl)-tetrakis(trimethylsilyl)disilane, which can be best explained by head-to-head dimerization of a silene intermediate arising from the Peterson-type reaction. Benzoyltris(trimethylsilyl)silane also reacted with methyllithium to give 1-(1-phenylethenyl)-2-(1-phenylethyl)-1,1,2,2-tetrakis(trimethylsilyl)disilane and (E)-3,4-dimethyl-3,4-diphenyl-1,1,2,2-tetrakis(trimethylsilyl)-1,2-disilacyclobutane. The reaction of pivaloyltris(trimethylsilyl)silane with methyllithium afforded products arising from the cleavage of an acyl-silicon bond.

引用

页码：3775 / 3776

页数：2

共 7 条

[1] PHOTOLYSIS OF ACYLPOLYSILANES CONTAINING ALPHA-HYDROGENS - FORMATION OF LINEAR HEAD-TO-HEAD SILENE DIMERS [J].