THEORETICAL INTERPRETATION OF THE LINE-SHAPE OBTAINED BY DYNAMIC POLARIZATION IN SOLUTIONS OF FREE-RADICALS

被引：13

作者：

AYANT, Y ^{[1
]}

BESSON, R ^{[1
]}

CASALEGNO, R ^{[1
]}

机构：

[1] CEN,LETI MA,F-38041 GRENOBLE,FRANCE

来源：

JOURNAL DE PHYSIQUE | 1980年 / 41卷 / 10期

关键词：

D O I：

10.1051/jphys:0198000410100118300

中图分类号：

学科分类号：

摘要：

Dynamic polarization of protons of solutions containing nitroxide free radicals in low field was previously studied with the help of hypotheses justified here. It is shown that the formalism of populations is a good approximation of the more complicated formalism of the density matrix. These available results are used to calculate theoretically the shape of the nuclear signal when the electronic frequency of excitation is varied. The obtained line-shape shows a dissymmetry in good agreement with that of the experimental one when the coherent radiation of the protonic spins is eliminated.

引用

页码：1183 / 1192

页数：10

共 10 条

[1] ABRAGAM A, 1961, PRINCIPES MAGNETISME, V8
[2] ANGOT A, 1965, COMPLEMENTS MATH, P688
[3] ATKINS PW, 1966, J CHEM PHYS, V44, P154
[4] EXPERIMENTAL AND THEORETICAL STUDIES OF LINE-WIDTH IN EPR OF DISSOLVED TANONE
AYANT, Y
BESSON, R
SALVI, A
[J]. JOURNAL DE PHYSIQUE, 1975, 36 (06): : 571 - 580
[5] EFFECT OF RELAXATION PROCESS ON COEFFICIENT OF DYNAMIC POLARIZATION IN SOLUTIONS OF FREE-RADICALS IN LOW FIELDS
AYANT, Y
CASALEGNO, R
[J]. JOURNAL DE PHYSIQUE, 1978, 39 (03): : 235 - 245
[6] BESSON R, 1973, THESIS U GRENOBLE
[7] BRIERE R, 1967, B SOC CHIM FR, V12, P4479
[8] SECHEHAYE R, 1974, THESIS GENEVE
[9] SLICHTER CP, PRINCIPLES MAGNETIC, V5
[10] WILSON R, 1966, J CHEM PHYS, V44, P169

← 1 →