OXIDE-BASE ADDUCTS OF ALUMINUM - X-RAY CRYSTAL-STRUCTURES OF ME3AL(OPPH3), ME3AL(ONME3) AND [(CH3)3SIO]3AL(OPPH3)

被引：24

作者：

FEHER, FJ

BUDZICHOWSKI, TA

WELLER, KJ

机构：

[1] Department of Chemistry, University of California, Irvine

来源：

POLYHEDRON | 1993年 / 12卷 / 06期

关键词：

D O I：

10.1016/S0277-5387(00)84973-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystalline molecular structures of three Lewis adducts of aluminum are reported. The structures of the 1 : 1 adducts between trimethylaluminum and triphenylphosphine oxide, 1: Me3Al(OPPh3), trimethylaluminum and trimethylamine-N-oxide; 2: Me3Al(ONMe3); and 3: [(CH3)3SiO]3Al(OPPh3) are discussed, and a comparison is made to the previously characterized aluminosilsesquioxane complex (C-C6H11)7 Si7O12Al(OPPh3) (5).

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页码：591 / 599

页数：9

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