THE DIASTEREOSELECTIVE SYNTHESIS OF (+)-ACTINOBOLIN FROM D-GLUCOSE

被引：15

作者：

WARD, DE

KALLER, BF

机构：

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 03期

关键词：

ACTINOBOLIN; BACTOBOLIN; 3+3] ANNULATION; 4,6-DIDEOXY-4-GALACTOSAMINE; DIASTEREOSELECTIVE SYNTHESIS;

D O I：

10.1016/0040-4039(93)85088-E

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The carbocyclic ring of actinobolin was constructed by a [3+3] annulation of a D-galactosamine derivative with 3-phenylthio-2-(trimethylsilylmethyl)propene. Formation of the lactone and acylation with L-alanine according to literature precedent gave (+)-actinobolin.

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页码：407 / 410

页数：4

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