NICKEL ADSORPTION TO HYDROUS FERRIC-OXIDE IN THE PRESENCE OF EDTA - EFFECTS OF COMPONENT ADDITION SEQUENCE

被引:63
作者
BRYCE, AL [1 ]
KORNICKER, WA [1 ]
ELZERMAN, AW [1 ]
CLARK, SB [1 ]
机构
[1] CLEMSON UNIV,LG RICH ENVIRONM RES LAB,CLEMSON,SC 29634
关键词
D O I
10.1021/es00062a020
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Nickel, EDTA, and hydrous ferric oxide were combined in different sequences to study the effect on equilibration. In this system, the fraction of nickel adsorbed to the hydrous ferric oxide depended on the component addition sequence, but the fraction of EDTA adsorbed did not. In one sequence, nickel and EDTA were combined to preform a NiEDTA2- complex. The complex had adsorption characteristics similar to EDTA with high adsorption at pH <7 and suppressed adsorption at pH > 7. Equilibrium adsorption of the complex could be modeled using the diffuse layer model. When nickel or EDTA was individually equilibrated with HFO prior to the addition of EDTA or nickel, respectively, the system did not attain equilibrium. Rapid EDTA adsorption at pH <7 prevented the formation of the ternary Ni-EDTA surface complex. At pH >7, nickel adsorption was faster than the formation of the NiEDTA2- complex, but once adsorbed, nickel was slowly desorbed through the formation of solution NiEDTA2-.
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页码:2353 / 2359
页数:7
相关论文
共 40 条
[1]  
Allison J.D., 1990, MINTEQA2PRODEFA2 GEO
[2]  
[Anonymous], 1990, SURFACE COMPLEXATION
[3]   REACTION-KINETICS OF THE ADSORPTION AND DESORPTION OF NICKEL, ZINC AND CADMIUM BY GOETHITE .2. MODELING THE EXTENT AND RATE OF REACTION [J].
BARROW, NJ ;
GERTH, J ;
BRUMMER, GW .
JOURNAL OF SOIL SCIENCE, 1989, 40 (02) :437-450
[4]   CONCEPTUAL-MODEL FOR METAL-LIGAND-SURFACE INTERACTIONS DURING ADSORPTION [J].
BENJAMIN, MM ;
LECKIE, JO .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1981, 15 (09) :1050-1057
[5]   EFFECTS OF COMPLEXATION BY CL, SO4, AND S2O3 ON ADSORPTION BEHAVIOR OF CD ON OXIDE SURFACES [J].
BENJAMIN, MM ;
LECKLE, JO .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1982, 16 (03) :162-170
[6]  
BOURG ACM, 1978, CHIMIA, V32, P166
[7]   ADSORPTION CHARACTERISTICS OF POLYACETIC AMINO-ACIDS ONTO HYDROUS GAMMA-AL2O3 [J].
BOWERS, AR ;
HUANG, CP .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1985, 105 (01) :197-215
[8]   ADSORPTION CHARACTERISTICS OF METAL-EDTA COMPLEXES ONTO HYDROUS OXIDES [J].
BOWERS, AR ;
HUANG, CP .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1986, 110 (02) :575-590
[9]  
BRIGHT GM, 1992, THESIS CLEMSON U
[10]   REACTION-KINETICS OF THE ADSORPTION AND DESORPTION OF NICKEL, ZINC AND CADMIUM BY GOETHITE .1. ADSORPTION AND DIFFUSION OF METALS [J].
BRUEMMER, GW ;
GERTH, J ;
TILLER, KG .
JOURNAL OF SOIL SCIENCE, 1988, 39 (01) :37-52