HIGH-FREQUENCY EFFECTS IN SPIN RELAXATION OF DIATOMIC GASES

被引：20

作者：

CHEN, FM

SNIDER, RF

机构：

[1] Department of Chemistry, University of British Columbia, Vancouver

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 09期

关键词：

D O I：

10.1063/1.1671668

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The high-frequency effects on NMR relaxation times due to the coherence between different rotational j states is considered. It is shown how steps in the Ti/ρ-vs-ρ curve can arise as a result of this mechanism. A generalized Boltzmann equation valid for density matrices nondiagonal in j states is required for this treatment, and this equation is briefly presented.

引用

页码：4082 / &

共 13 条

[1]

ALEXANDER S, PRIVATE COMMUNICATIO

[2] NUCLEAR SPIN RELAXATION IN GASEOUS METHANE AND ITS DEUTERATED MODIFICATIONS [J].