ELECTRONIC-STRUCTURE AND REACTIVITY OF PROPELLANES - PHOTOELECTRON-SPECTRA OF THIA[4.4.3]PROPELLANES

被引：7

作者：

BOHM, MC ^{[1
]}

GLEITER, R ^{[1
]}

机构：

[1] TH DARMSTADT,INST ORGAN CHEM,D-6100 DARMSTADT,FED REP GER

来源：

TETRAHEDRON | 1979年 / 35卷 / 05期

关键词：

D O I：

10.1016/0040-4020(79)87015-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photoelectron spectra of 12-thia[4.4.3]propell-3-ene (), 12-thia[4.4.3]propell-3-ene-12-oxide (2), 12-thia[4.4.3]propella-3,8-diene-12-oxide (3), 12-thia[4.4.3]propella-3,8-diene-12-dioxide (4), 12 thia[4.4.3]propella-2, 4-diene-12-oxide (5), 12-thia(4.4.3]propella-2,4,7,9 tetraene-12-oxide (6) and 12-thia[4.4.3]propella-2,4,7,9 tetraene-12-dioxide (7) have been investigated and the first bands have been interpreted. For compounds 3 and 4 the endo-endo conformation could be excluded. For 6 and 7 the interaction of the two butadiene moieties is of the same order as that of the π-orbitals in norbornadiene. The electronic structure of 3 and 4 allows us to rationalize and to predict the direction of the addition of cations and carbenes. © 1979.

引用

页码：675 / 679

页数：5

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