SYNTHESIS AND REACTIVITY OF PROTECTED BETA-BROMO ALPHA-IMINOACIDS - A CONVENIENT ROUTE TO STRUCTURALLY DIVERSIFIED AMINO-ACIDS

被引：26

作者：

DANIONBOUGOT, R ^{[1
]}

DANION, D ^{[1
]}

FRANCIS, G ^{[1
]}

机构：

[1] UNIV RENNES 1,CNRS,RECH PHYSICOCHIM STRUCT GRP,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(00)97458-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compounds are obtained by N-bromosuccinimide oxidation of protected didehydroaminoacids. Additions to the imino group are readily performed with borohydride, Grignard reagents or other nucleophiles. Heterocyclic aminoacids are available by subsequent displacement of bromine. © 1990.

引用

页码：3739 / 3742

页数：4

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