REACTIONS OF SMALL MOLECULES WITH TRANSITION-METAL CLUSTER HYDRIDES - REACTION OF H2OS3(CO)10 WITH ARYL-ISOCYANATES AND ARYL-ISOTHIOCYANATES

被引：27

作者：

ADAMS, RD

GOLEMBESKI, NM

机构：

[1] Department of Chemistry, Yale University, New Haven

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 171卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)88076-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The transition metal cluster hydride complex H2Os3(CO)10 reacts with aryl isocyanates and isothiocyanates to yield products containing N-aryl-formamido and -thioformamido ligands. The compound (μ-p-CH3C6H4NC(H)O) (μ-H)Os3(CO)10 has been analyzed by x-ray crystallographic methods and is shown to contain a formamido ligand bridging the edge of the triosmium cluster. © 1979.

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页码：C21 / C26

页数：6

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