SYNTHESIS OF OPTICALLY-ACTIVE CYCLOBUTANONES BY THE PHOTOLYSIS OF CHROMIUM ALKOXYCARBENE COMPLEXES IN THE PRESENCE OF OPTICALLY-ACTIVE ENE CARBAMATES

被引：81

作者：

HEGEDUS, LS

BATES, RW

SODERBERG, BC

机构：

[1] Department of Chemistry, Colorado State University, Fort Collins

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 03期

关键词：

D O I：

10.1021/ja00003a027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optically active ene-carbamates derived from (S)-phenylglycine were allowed to photochemically react with a variety of (alkoxy)(alkyl)chromium-carbene complexes. Cyclobutanones were formed in fair to good yield with generally excellent control of stereochemistry.

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页码：923 / 927

页数：5

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