MOLECULAR RECOGNITION OF PRIMARY AMINES BY 3-POINT BINDING WITH BORON-CONTAINING HOST MOLECULES

被引：36

作者：

REETZ, MT

NIEMEYER, CM

HERMES, M

GODDARD, R

机构：

[1] Max-Planck-Institut Für Kohlenforschung, Mülheiman, D-W-4330

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 08期

关键词：

D O I：

10.1002/anie.199210171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible formation of a dative bond between the boron center (M) of the host and the N atom of the primary amine, with simultaneous formation of hydrogen bonds between the amine H atoms and two oxygen atoms (D) of the crown ether host presents a new concept in molecular recognition (depicted schematically right). The control of the degree and direction of the molecular recognition by variation of the groups R on the amine is unprecedented.

引用

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页码：1017 / 1019

页数：3

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