PT+-MEDIATED ACTIVATION OF METHANE - THEORY AND EXPERIMENT

被引：104

作者：

HEINEMANN, C

WESENDRUP, R

SCHWARZ, H

机构：

[1] Institut für Organische Chemie der Technischen Universität Berlin, D-10623 Berlin

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 239卷 / 1-3期

关键词：

D O I：

10.1016/0009-2614(95)00446-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A combined theoretical and experimental study on the Pt+-mediated activation of methane is presented. Dehydrogenation of CH2 by thermalized Pt+ cations (Pt++ CH4 reversible arrow PtCH2++ H-2) proceeds along a doublet ground state potential energy surface and is found to be reversible under the conditions of Fourier transform ion-cyclotron resonance mass spectrometry. The recently reported oxidation of the cationic platinum carbene PtCH2+ by O-2 produces electronically excited Pt+ cations, which are detected in the F-4(9/2) state by means of charge-transfer bracketing experiments.

引用

页码：75 / 83

页数：9

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