TOTAL SYNTHESES OF (+)-NONACTATE AND (-)-NONACTATE ESTERS USING SILICON-COMPOUNDS TO CONTROL THE STEREOCHEMISTRY

被引：27

作者：

FLEMING, I

GHOSH, SK

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 19期

关键词：

D O I：

10.1039/c39940002285

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3-Transposition, using the epoxidation of the allylsilane 7, derived from the meso 3,4-disilylated adipate 1, gives the 1,4-related stereocentres of 8-oxo-6-hydroxy-3-dimethyl(tolyl)silylnonanoic acid ethylene acetal 10; two highly stereocontrolled sequences from this common intermediate give methyl (+)-nonactate 13 and benzyl (-)-nonactate 17.

引用

页码：2285 / 2286

页数：2

共 28 条

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