REACTIONS OF "CYCLOPENTADIENYLCARBONYLALKYNYLIRON COMPOUNDS WITH ELECTROPHILES .2. CYCLO-ADDITION REACTIONS WITH TETRACYANOETHYLENE AND HEXAFLUOROACETONE

被引：65

作者：

DAVISON, A

SOLAR, JP

机构：

[1] Department of Chemistry, Massachusetts Institute of Technology, Cambridge

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 166卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)91429-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclopentadienylcarbonylalkynylirons react with the neutral elec̀trophiles tetracyanoethylene and hexafluoroacetone. These reactions lead to a (2 + 2) cycloaddition to the alkynyl ligand and involve a two step mechanism. Initial electrophilic attack forms a dipolar complex which by a cyclization reaction can form a σ-cyclobutenyl complex. © 1979.

引用

页码：C13 / C17

页数：5

共 8 条

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