FLUORINATED GAMMA-ALUMINA - CATALYTIC FLUORINATION OF 1,1,1-TRICHLOROETHANE AT AMBIENT-TEMPERATURE

被引：20

作者：

THOMSON, J ^{[1
]}

WEBB, G ^{[1
]}

WINFIELD, JM ^{[1
]}

机构：

[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 05期

关键词：

D O I：

10.1039/c39910000323

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

gamma-Alumina, fluorinated with sulphur tetrafluoride followed by treatment with 1,1,1-trichloroethane, behaves as a catalyst for the room temperature fluorination of CH3CCl3 with anhydrous HF, giving a mixture of chlorofluorohydrocarbons.

引用

页码：323 / 324

页数：2

共 6 条

[1] ACIDIC PROPERTIES OF SILICA-ALUMINA GELS AS A FUNCTION OF CHEMICAL COMPOSITION - TITRATION AND CATALYTIC ACTIVITY MEASUREMENTS [J].

DAMON, JP ;

DELMON, B ;

BONNIER, JM .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1977, 73 :372-380

[2]

Goble A. G., 1964, P INT C CATAL, P320

[3] ALUMINUM(III) CHLORIDE CHLOROHYDROCARBON CHEMISTRY - FOURIER-TRANSFORM INFRARED SPECTROSCOPIC STUDIES OF THE REACTIONS BETWEEN SOLID ALUMINUM(III) CHLORIDE AND 1,1,1-TRICHLOROETHANE OR 1,1-DICHLOROETHENE VAPORS [J].

MCBETH, DG ;

WINFIELD, JM ;

COOK, BW ;

WINTERTON, N .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (02) :671-676

[4]

MIALE JN, 1984, Patent No. 4427191

[5] RADIOTRACERS IN FLUORINE CHEMISTRY .13. CATALYSIS BY FLUORINATED SURFACES - THE INTERACTION OF [CL-36] CHLORINE LABELED HYDROGEN-CHLORIDE AND 1,1-DICHLOROTETRAFLUOROETHANE WITH FLUORINATED CHROMIA CATALYSTS [J].

ROWLEY, L ;

WEBB, G ;

WINFIELD, JM ;

MCCULLOCH, A .

APPLIED CATALYSIS, 1989, 52 (1-2) :69-80

[6]

THOMSON J, IN PRESS J MOL CATAL

← 1 →