SYNTHESIS OF IODOALKYLIDENE LACTONES FROM ALKENES

被引：14

作者：

HAAIMA, G ^{[1
]}

LYNCH, MJ ^{[1
]}

ROUTLEDGE, A ^{[1
]}

WEAVERS, RT ^{[1
]}

机构：

[1] UNIV OTAGO,DEPT CHEM,BOX 56,DUNEDIN,NEW ZEALAND

来源：

TETRAHEDRON | 1993年 / 49卷 / 20期

关键词：

D O I：

10.1016/S0040-4020(01)85740-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkenes are readily transformed into iodo acetylenic esters by addition of acetylenic acids in the presence of a source of iodonium ion. A subsequent free-radical cyclisation induced by dibenzoyl peroxide leads to (E)-iodoalkylidene butyrolactones.

引用

页码：4229 / 4252

页数：24

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