SYNTHESIS OF CHIRAL BITETRALIN-STRAPPED TWIN CORONET PORPHYRINS - CATALYTIC AND ASYMMETRIC EPOXIDATION OF STYRENE DERIVATIVES

被引:16
作者
NARUTA, Y
ISHIHARA, N
TANI, F
MARUYAMA, K
机构
关键词
D O I
10.1246/cl.1991.1933
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Twin-coronet porphyrins bearing optically active 1,1'-bitetrahydronaphthalene derivatives on the both faces of the porphyrin were prepared as enantioselective oxidation catalysts modeling on cytochrome P-450s. The eclipsed isomer of the corresponding iron(III) porphyrins catalyzed epoxidation of styrenes substituted with electron-withdrawing groups in high e.e. (61-89%) and high product selectivity.
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页码:1933 / 1936
页数:4
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