THE REACTION OF [CP2+NB2(B2H6)2] (CP+ = ETA-ETME4C5) WITH SULFUR - STABILIZATION OF THE TETRATHIOBORATO LIGAND IN NOVEL SULFIDO NIOBIUM CLUSTERS

被引：14

作者：

BRUNNER, H

GEHART, G

NUBER, B

WACHTER, J

ZIEGLER, ML

机构：

[1] UNIV REGENSBURG,INST ANORGAN CHEM,UNIV STR 31,W-8400 REGENSBURG,GERMANY

[2] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 08期

关键词：

D O I：

10.1002/anie.199210211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An equilateral Nb3 triangle the edges of which are spanned by a BS4 tetrahedron and bridged by sulfido ligands on the "underside" is found in cluster 1. The synthesis of this cluster with an unusual electron configuration shows that tetrathioborates can serve as ligands in organometallic chemistry. Cp+ = eta-5-EtMe4C5.

引用

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页码：1021 / 1023

页数：3

相关论文

共 16 条

[1]

BERCAW JE, COMMUNICATION

[2]

BERCAW JE, 1982, COMPREHENSIVE ORGANO, V3, P765

[3] [(BH2)6S4]2-, [(BH2)6SE4]2- - NEW CHALCOGENOBORON HYDRIDE ANIONS WITH ADAMANTANE STRUCTURE [J].

BINDER, H ;

LOOS, H ;

DERMENTZIS, K ;

BORRMANN, H ;

SIMON, A .

CHEMISCHE BERICHTE, 1991, 124 (03) :427-432

[4] ORGANOMETALLIC OXIDES - PREPARATION AND PROPERTIES OF THE DIAMAGNETIC TRINUCLEAR CLUSTER ([(ETA-C5ME5)NB(MU-CL)(MU-O)]3)+ AND RELATED CHLORIDE OXIDES OF NIOBIUM [J].

BOTTOMLEY, F ;

KARSLIOGLU, S .

ORGANOMETALLICS, 1992, 11 (01) :326-337

[5] ORGANOMETALLIC OXIDES - PREPARATION, STRUCTURE, AND CHEMICAL AND PHYSICAL-PROPERTIES OF PARAMAGNETIC [(ETA-C5H5)NBCL(MU-A)]3(MU-3-OH)(MU-3-O) (A = CL, OH) AND OTHER OXO-HYDROXO CLUSTERS OF NIOBIUM [J].

BOTTOMLEY, F ;

KEIZER, PN ;

WHITE, PS ;

PRESTON, KF .

ORGANOMETALLICS, 1990, 9 (06) :1916-1925

[6] NEW ASPECTS IN THE CHEMISTRY OF TRANSITION-METAL POLYSULFIDE COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURES OF CP'3NB3S12 AND CP'3NB3S10 O, WHERE CP'=T-BUC5H4 [J].

BRUNNER, H ;

MEIER, W ;

WACHTER, J ;

NUBER, B ;

ZIEGLER, ML .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 381 (01) :C7-C12

[7]

BRUNNER H, IN PRESS J ORGANOMET

[8] STRUCTURAL CHARACTERIZATION OF PARAMAGNETIC, TRIANGULO NIOBIUM CLUSTERS, CP'3NB3CL3(MU-2-CL)3(MU-3-O)(MU-3-OH), CP'3NB3CL3(MU-2-CL)3(MU-3-O)(MU-3-CL) [J].

CURTIS, MD ;

REAL, J .

INORGANIC CHEMISTRY, 1988, 27 (18) :3176-3180

[9]

GIBSON VC, 1986, ORGANOMETALLICS, V5, P972

[10] MULTIPLE BONDS BETWEEN MAIN GROUP ELEMENTS AND TRANSITION-METALS .14. REDUCTIVE TRIMERIZATION OF THE TRIOXO HALF-SANDWICH COMPLEX [ETA-5-C5ME5)REO3] WITH DEOXYGENATION - THE ELECTRON-DEFICIENT CLUSTER ION [(ETA-5-C5ME5)3RE3(MU-O)6]2+ [J].

HERRMANN, WA ;

SERRANO, R ;

ZIEGLER, ML ;

PFISTERER, H ;

NUBER, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (01) :50-52