SYNTHESIS OF MOLECULAR JACKS - RIGID TETRAHEDRAL MOLECULES WITH P-PHENYLENE ARMS

被引：51

作者：

WILSON, LM ^{[1
]}

GRIFFIN, AC ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,MELVILLE LAB POLYMER SYNTH,PEMBROKE ST,CAMBRIDGE CB2 3RA,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1993年 / 3卷 / 09期

关键词：

TETRAHEDRAL MOLECULES; MOLECULAR JACKS; TETRAPHENYLMETHANE;

D O I：

10.1039/jm9930300991

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A family of rigid tetrahedral molecules based on tetraphenylmethane has been synthesized. The primary preparative chemistry involved Suzuki coupling. Reactions typically proceeded in good yields providing synthetic entry to tetrahedral building blocks for molecular engineering of architecturally regular macromolecular systems.

引用

页码：991 / 994

页数：4

共 11 条

[1] PREPARATION OF POLYMERS WITH CONTROLLED MOLECULAR ARCHITECTURE - A NEW CONVERGENT APPROACH TO DENDRITIC MACROMOLECULES [J].

HAWKER, CJ ;

FRECHET, JMJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (21) :7638-7647

[2] DESIGN AND CONSTRUCTION OF A NEW CLASS OF SCAFFOLDING-LIKE MATERIALS COMPRISING INFINITE POLYMERIC FRAMEWORKS OF 3-D-LINKED MOLECULAR RODS - A REAPPRAISAL OF THE ZN(CN)2 AND CD(CN)2 STRUCTURES AND THE SYNTHESIS AND STRUCTURE OF THE DIAMOND-RELATED FRAMEWORKS [N(CH3)4][CUIZNII(CN)4] AND CUI[4,4',4'',4'''-TETRACYANOTETRAPHENYLMETHANE]BF4.XC6H5NO2 [J].

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (04) :1546-1554

[3] WATER-SOLUBLE HYPERBRANCHED POLYPHENYLENE - A UNIMOLECULAR MICELLE [J].

KIM, YH ;

WEBSTER, OW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) :4592-4593

[4] SMALL RINGS .25. TETRA-TERT-BUTYLTETRAHEDRANE [J].

MAIER, G ;

PFRIEM, S ;

SCHAFER, U ;

MATUSCH, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (07) :520-521

[5] SYNTHESIS OF RIGID TETRAHEDRAL TETRAFUNCTIONAL MOLECULES FROM 1,3,5,7-TETRAKIS(4-IODOPHENYL)ADAMANTANE [J].

MATHIAS, LJ ;

REICHERT, VR ;

MUIR, AVG .

CHEMISTRY OF MATERIALS, 1993, 5 (01) :4-5

[6] SYNTHESIS AND CHARACTERIZATION OF A SERIES OF MONODISPERSE, 1,3,5-PHENYLENE-BASED HYDROCARBON DENDRIMERS INCLUDING C276H186 AND THEIR FLUORINATED ANALOGS [J].

MILLER, TM ;

NEENAN, TX ;

ZAYAS, R ;

BAIR, HE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (03) :1018-1025

[7] THE PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF PHENYLBORONIC ACID WITH HALOARENES IN THE PRESENCE OF BASES [J].

MIYAURA, N ;

YANAGI, T ;

SUZUKI, A .

SYNTHETIC COMMUNICATIONS, 1981, 11 (07) :513-519

[8] SYNTHESIS OF RIGID DENDRITIC MACROMOLECULES - ENLARGING THE REPEAT UNIT SIZE AS A FUNCTION OF GENERATION PERMITS GROWTH TO CONTINUE [J].

MOORE, JS ;

XU, ZF .

MACROMOLECULES, 1991, 24 (21) :5893-5894

[9] STARBURST DENDRIMERS - MOLECULAR-LEVEL CONTROL OF SIZE, SHAPE, SURFACE-CHEMISTRY, TOPOLOGY, AND FLEXIBILITY FROM ATOMS TO MACROSCOPIC MATTER [J].

TOMALIA, DA ;

NAYLOR, AM ;

GODDARD, WA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1990, 29 (02) :138-175

[10] EXTENDED ORTHOGONALLY FUSED CONDUCTING OLIGOMERS FOR MOLECULAR ELECTRONIC DEVICES [J].

TOUR, JM ;

WU, R ;

SCHUMM, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :7064-7066

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