2,2'-BIPYRIDINEDICHLOROGOLD(III) TETRAFLUOROBORATE

被引：26

作者：

MCINNES, EJL

WELCH, AJ

YELLOWLEES, LJ

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270195005099

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystallographically determined structure of the title compound, [AuCl2(C10H8N2)]BF4, is reported. The cation is approximately planar and of C-2 nu local symmetry. Both Au-Cl distances are 2.252 (4) A and the average Au-N distance is 2.037 (13) Angstrom. One pyridine ring of the bipyridyl ligand is hydrogen bonded to the adjacent BF4- anion, There is no significant cation-cation stacking in the solid state.

引用

页码：2023 / 2025

页数：3

共 10 条

[1]

GOULD RO, 1986, CADABS PROGRAM DATA

[2]

GOULD RO, 1986, CALC PROGRAM MOL GEO

[3]

HARRIS CM, 1959, J CHEM SOC, P3083

[4] ORIGIN OF POLYCHROMISM OF CIS-SQUARE-PLANAR PLATINUM(II) COMPLEXES - COMPARISON OF 2 FORMS OF [PT(2,2'-BPY)(CL)2] [J].

HERBER, RH ;

CROFT, M ;

COYER, MJ ;

BILASH, B ;

SAHINER, A .

INORGANIC CHEMISTRY, 1994, 33 (11) :2422-2426

[5]

MACGREGOR SA, 1993, NATO ADV SCI INST SE, V385, P503

[6] CRYSTAL-STRUCTURE OF RED FORM OF 2,2'-BIPYRIDYLDICHLOROPLATINUM(II) [J].

OSBORN, RS ;

ROGERS, D .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (09) :1002-1004

[7]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

[8]

SHELDRICK GM, 1990, SHELXTL USER MANUAL

[9] AN EMPIRICAL-METHOD FOR CORRECTING DIFFRACTOMETER DATA FOR ABSORPTION EFFECTS [J].

WALKER, N ;

STUART, D .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (JAN) :158-166

[10] SYNTHESES, CRYSTAL-STRUCTURES AND PHOTOPHYSICS OF ORGANOGOLD(III) DIIMINE COMPLEXES [J].

YAM, VWW ;

CHOI, SWK ;

LAI, TF ;

LEE, WK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (06) :1001-1002

← 1 →