NEW SYNTHETIC APPROACH TO 4-ALKYLIDENECYCLOHEXENES - REDUCTION-PROTODESILYLATION OF BENZYLSILANES

被引：47

作者：

COUGHLIN, DJ ^{[1
]}

SALOMON, RG ^{[1
]}

机构：

[1] CASE WESTERN RESERVE UNIV,DEPT CHEM,CLEVELAND,OH 44106

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 22期

关键词：

D O I：

10.1021/jo01336a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthetic methodology is described which allows conversion of benzylsilanes into 4-alkylidenecyclohexenes or 4-alkylidenecyclohexanones in good yields. Structurally specific syntheses are readily achieved for various derivatives which are not efficiently accessible by conventional methods. These include the natural product, terpinolene, as well as 2-methyl-4-methylenecyclohexan-l-one and 3-carbomethoxy-5-methylenecyclohex-l-ene. © 1979, American Chemical Society. All rights reserved.

引用

页码：3784 / 3790

页数：7

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