SYNTHESIS OF A DEOXYRISTOMYCINIC ACID-DERIVATIVE USING ORGANOMANGANESE CHEMISTRY

被引：26

作者：

PEARSON, AJ

LEE, SH

GOUZOULES, F

机构：

[1] Department of Chemistry, Case Western Reserve University, Cleveland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 08期

关键词：

D O I：

10.1039/p19900002251

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Coupling of (3-chloro-2-methylanisole)tricarbonylmanganese tetrafluoroborate with the phenoxide derived from methyl N-Boc-3- hydroxyphenylglycinate gave the diaryl ether manganese complex (6). This complex underwent regiospecific, stereoselective reaction with Schollkopf's chiral glycine enolate equivalent to give a mixture of dienyl-Mn(CO)3 complexes that were converted in a two-step sequence into the protected deoxyristomycinic acid derivative (12).

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页码：2251 / 2254

页数：4

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