ENHANCEMENT OF ETHYLENE HYDROFORMYLATION OVER NI SIO2 THROUGH SULFUR PROMOTION

被引：12

作者：

CHUANG, SSC

PIEN, SI

机构：

[1] Department of Chemical Engineering, University of Akron, Akron, 44325, OH

来源：

CATALYSIS LETTERS | 1990年 / 6卷 / 3-6期

关键词：

ethylene; Hydroformylation; infrared spectroscopy; propionaldehyde; sulfided nickel; synthesis gas;

D O I：

10.1007/BF00764006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sulfidation of Ni/SiO2 with H2S leads to a blockage of bridge-CO sites, an upward shift in the wavenumber of linearly adsorbed CO, an inhibition of ethylene hydrogenation, and an enhancement of the formation of propionaldehyde from ethylene hydroformylation. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.

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页码：389 / 394

页数：6

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