MAGNETIC-FIELD EFFECT ON THE RECOMBINATION OF THE TRIPLET RADICAL ION-PAIR STATE OF THE ZN-PORPHYRIN VIOLOGEN DYAD - THE INFLUENCE OF THE SUPRAMOLECULE MICROENVIRONMENT

被引：11

作者：

SHAFIROVICH, VY ^{[1
]}

BATOVA, EE ^{[1
]}

LEVIN, PP ^{[1
]}

机构：

[1] ACAD SCI USSR,INST CHEM PHYS,MOSCOW 117334,USSR

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 172卷 / 01期

关键词：

D O I：

10.1016/0009-2614(90)87208-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photochemical behaviour of the semirigid Zn-porphyrin-violegen dyad depends on its microenvironment which affects the rate of the dyad conformational transitions and the radical ion pair (RIP) triple-singlet splitting in zero magnetic field. The heavy-atom environment of RIP enhances the RIP recombination and quenches the magnetic field effect. © 1990.

引用

页码：10 / 16

页数：7

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