DEHYDRATION OF WATER PYRIDINE MIXTURES BY PERVAPORATION

被引:22
作者
KUJAWSKI, W [1 ]
NGUYEN, TQ [1 ]
NEEL, J [1 ]
机构
[1] INST NATL POLYTECH LORRAINE,ECOLE NATL SUPER IND CHIM,CHIM PHYS MACROMOLEC LAB,CNRS,UA 494,F-54001 NANCY,FRANCE
关键词
D O I
10.1080/01496399108050517
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Several ion-exchange and neutral membranes were examined in the pervaporation of water-pyridine mixtures. Carboxylic and sulfonic ion-exchange membranes were used with hydrogen counterion and additionally with trimethylammonium, triethylammonium, and tributylammonium counterions. All membranes were selective to water, but the transport mode and selectivity properties of membranes were dependent on both the character of the ion-exchange group and the ionic form of the membrane. The results obtained suggest that pervaporation of water-pyridine mixtures could be used with standard distillation in the large-scale dehydration process of pyridine.
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页码:1109 / 1121
页数:13
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