SYNTHESIS OF 1,2,4-TRIOXANES VIA INTRAMOLECULAR OXYMERCURIATION

被引：46

作者：

BLOODWORTH, AJ

SHAH, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 14期

关键词：

D O I：

10.1039/c39910000947

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3-Alkyl- and 3-aryl-5,5,6,6-tetramethyl-1,2,4-trioxanes 5 are prepared by reduction of the corresponding 5-bromomercuriomethyl compounds 4 obtained, after anion exchange, by intramolecular oxymercuriation of the hemiperacetals 3 formed from aldehydes and 2,3-dimethylbut-1-en-3-yl hydroperoxide 2; a 'one pot' procedure omitting the anion exchange and isolation of the organomercury(II) bromide 4 may be used.

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页码：947 / 948

页数：2

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