AN EFFICIENT AND STEREOSELECTIVE SYNTHESIS OF INSECT PHEROMONES BY WAY OF NICKEL-CATALYZED GRIGNARD REACTIONS - SYNTHESES OF GOSSYPLURE AND PHEROMONES OF EUDIA-PAVONIA AND DROSOPHILA-MELANOGASTER

被引：11

作者：

DUCOUX, JP

LEMENEZ, P

KUNESCH, N

KUNESCH, G

WENKERT, E

机构：

[1] FAC PHARM CHATENAY MALABRY,CHIM SUBSTANCES THERAPEUT NAT LAB,F-92296 CHATENAY MALABRY,FRANCE

[2] UNIV PARIS 11,CHIM COORDINAT BIOORGAN & BIOINORGAN LAB,CNRS,URA 1384,F-91405 ORSAY,FRANCE

[3] UNIV CALIF SAN DIEGO,DEPT CHEM 0506,LA JOLLA,CA 92093

来源：

TETRAHEDRON | 1992年 / 48卷 / 31期

关键词：

D O I：

10.1016/S0040-4020(01)88230-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three pheromones, (6Z,11Z)-hexadeca-6.11-dien-1-yl acetate (from Eudia pavonia), (5Z,9Z)-heptacosa-5,9-diene (from Drosophila melanogaster) and gossyplure, have been synthesized each by two consecutive sequences of nickel-assisted Grignard reactions with cyclic enol ethers and preparation of Grignard reagents from the resultant alcohols.

引用

页码：6403 / 6412

页数：10

共 37 条

[1] A PRACTICAL SYNTHESIS OF GOSSYPLURE, THE SEX-PHEROMONE OF THE PINK-BOLLWORM MOTH (PECTINOPHORA-GOSSYPIELLA) [J].