RHODIUM(II)-VINYLCARBENOID INSERTION INTO THE SI-H BOND - A NEW STEREOSPECIFIC SYNTHESIS OF ALLYLSILANES

被引：52

作者：

LANDAIS, Y

PLANCHENAULT, D

WEBER, V

机构：

[1] Institut de Chimie Organique, Université de Lausanne Collège Propédeutique

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 51期

关键词：

D O I：

10.1016/0040-4039(94)88508-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rh-2(OAc)(4) catalysed decomposition of vinyldiazocarbonyl compounds in the presence of organosilanes led stereospecifically to the corresponding allylsilanes in good yields. An asymmetric approach has also been considered as well as the extension of the methodology to the synthesis of other allylic systems.

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页码：9549 / 9552

页数：4

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