DILATOMETRIC STUDY OF KINETICS OF POLYMERIZATION OF PURE META-DIVINYLBENZENES AND PURE PARA-DIVINYLBENZENES

被引：6

作者：

WILEY, RH

JIN, JI

AHN, TO

机构：

[1] Department of Chemistry Hunter, College of the City University of New York, New York

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1969年 / A 3卷 / 08期

关键词：

D O I：

10.1080/10601326908051951

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A comparison of the dilatometrically determined rates of polymerization of pure meta-and pure para-divinylbenzenes confirms the previous observation that the meta isomer polymerizes more rapidly than the para isomer. This difference shows up also in the initiator square root rate dependencies, the gel times, and the conversions at gel point. The effect of added regulator (carbon tetrabromide) on the polymerization of the meta isomer is to decrease the gel time and conversion at gel time. © 1969, Taylor & Francis Group, LLC. All rights reserved

引用

页码：1543 / &

共 7 条

[1] THE NON-STATIONARY PHASE OF CHAIN REACTIONS .1. THE PHOTOPOLYMERIZATION OF STYRENE [J].