CHARACTERISTIC EFFECTS IN THE REACTION-KINETICS OF POLYMERIC REAGENTS

被引：13

作者：

MORAWETZ, H

机构：

[1] Department of Chemistry, Polytechnic Institute of New York, Brooklyn, N.Y.

来源：

PURE AND APPLIED CHEMISTRY | 1979年 / 51卷 / 12期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1351/pac197951122307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent advances in studies of the kinetics of chemical processes in dilute polymer solutions include investigations of hindered rotation in the backbone of flexible chain molecules, of ionic reactions in polyelectrolyte solutions, kinetic effects reflecting the local medium in the polymer domain, neighboring group effects in reactions of poly-saccharides and diffusion-controlled intramolecular or intermolecular reactions. In addition, some results are presented on the kinetics of reactions of gel-bound reactive groups with reagents in homogeneous solution. © 1979, Walter de Gruyter. All rights reserved.

引用

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页码：2307 / 2311

页数：5

相关论文

共 39 条

[1] ROLE OF INTERNAL VISCOSITY IN POLYMER VISCOELASTICITY [J].

ALLEGRA, G .

JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (11) :4910-4920

[2] A SIMPLE DILATOMETRIC METHOD OF DETERMINING THE RATE CONSTANTS OF CHAIN REACTIONS .2. THE EFFECT OF VISCOSITY ON THE RATE CONSTANTS OF POLYMERIZATION REACTIONS [J].

BENSON, SW ;

NORTH, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (06) :1339-1345

[3] KINETICS OF FREE RADICAL POLYMERIZATION UNDER CONDITIONS OF DIFFUSION-CONTROLLED TERMINATION [J].

BENSON, SW ;

NORTH, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (06) :935-&

[4] INTRAMOLECULAR EXCIMERS AND MICRO-BROWNIAN MOTION OF FLEXIBLE POLYMER-MOLECULES IN SOLUTION [J].

CUNIBERTI, C ;

PERICO, A .

EUROPEAN POLYMER JOURNAL, 1977, 13 (05) :369-374

[5] PHASE-TRANSFER CATALYZED 2-PHASE REACTIONS IN PREPARATIVE ORGANIC-CHEMISTRY [J].

DEHMLOW, EV .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1974, 13 (03) :170-179

[6] ADVANCES IN PHASE-TRANSFER CATALYSIS [J].

DEHMLOW, EV .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (08) :493-505

[7] INTRA-MOLECULAR EXCIMER STUDY OF RATES OF CONFORMATIONAL TRANSITIONS - DEPENDENCE ON MOLECULAR-STRUCTURE AND VISCOSITY OF MEDIUM [J].

GOLDENBERG, M ;

EMERT, J ;

MORAWETZ, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (23) :7171-7177

[8]

HAMMER PC, 1977, J POLYM SCI PP, V15, P321

[9] THEORY OF KINETICS OF CONFORMATIONAL TRANSITIONS IN POLYMERS [J].

HELFAND, E .

JOURNAL OF CHEMICAL PHYSICS, 1971, 54 (11) :4651-+

[10] TRIPLET PROBE STUDY OF EXCLUDED VOLUME EFFECT ON RATES OF DIFFUSION-CONTROLLED INTERMACROMOLECULAR REACTIONS BETWEEN CHAIN END GROUPS OF POLYSTYRENE [J].

HORIE, K ;

MITA, I .

MACROMOLECULES, 1978, 11 (06) :1175-1179

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