CRYSTAL-STRUCTURE OF TRIPHENYLPHOSPHINE OXIDE

被引：64

作者：

ALFARHAN, KA

机构：

[1] Chemistry Department, King Saud University, Riyadh

来源：

JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH | 1992年 / 22卷 / 06期

关键词：

D O I：

10.1007/BF01160986

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of Triphenylphosphine Oxide, C18H15PO, was reinvestigated using Mo-Kalpha radiation lambda = 0.71069 angstrom, mu(Mo-Kalpha) = 1.36 cm-1. M(r) = 278.1, orthohombic, Pbca, a = 29.089(3), b = 9.1347(9), c = 11.261(1) angstrom, V = 2992.2 angstrom3, Z = 4, D(x) = 1.235 Mg m-3. The structure was refined by full-matrix least-squares to R = 0.040 and R(w) = 0.036 for 1848 unique reflections and 182 variables. Improved bond lengths and angles were obtained; O-P is 1.479(2) angstrom, weighted means of P-C is 1.803(1) angstrom, O-P-C is 112.6(1)-degrees and C-P-C is 106.2(1)-degrees.

引用

页码：687 / 689

页数：3

共 16 条

[1] PREPARATION, PROPERTIES, AND REACTIONS WITH SULFUR-DIOXIDE OF TRIPHENYLPHOSPHINE OXIDE COMPLEXES OF MANGANESE(II) THIOCYANATE - CRYSTAL-STRUCTURES OF [(MN(OPPH3)2(NCS)(MU-NCS))2], [MN(OPPH3)4(NCS)2], AND (PPH3O)(PPH3OH)(HSO4), A DERIVATIVE OF SULFURIC-ACID FORMED UNDER AMBIENT AIR OXIDATION OF SULFUR-DIOXIDE [J].

ALFARHAN, K ;

BEAGLEY, B ;

ELSAYRAFI, O ;

GOTT, GA ;

MCAULIFFE, CA ;

MACRORY, PP ;

PRITCHARD, RG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (04) :1243-1250

[2]

ALFARHAN K, 1988, XRAY STUDIES MANGANE

[3]

ANTIPIN MY, 1980, KRISTALLOGRAFIYA+, V25, P514

[4] CRYSTAL AND MOLECULAR STRUCTURE OF TRIPHENYLPHOSPHINE OXIDE [J].

BANDOLI, G ;

BORTOLOZZO, G ;

CLEMENTE, DA ;

CROATTO, U ;

PANATTON.C .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (17) :2778-+

[5] CRYSTAL + MOLECULAR STRUCTURE OF TRIPHENYL-PHOSPHORUS [J].

DALY, JJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (OCT) :3799-&

[6]

DAVENPORT G, 1990, LSQPL XTAL 3 0 REFER

[7]

EDWARD P, 1982, MATH TECHNIQUES CRYS, P97

[8]

KELLER E, 1988, SCHAKAL 88BV16 KRIST

[9]

OLTHOFHAZEKAP R, 1990, NEWMAN XTAL 3 0 REFE

[10]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

← 1 2 →