NEAR-INFRARED FOURIER-TRANSFORM RAMAN MICROSPECTROSCOPY AT HIGH EXTERNAL PRESSURES

被引：7

作者：

BARNETT, SM

MARKWELL, RD

BRIENNE, SHR

BUTLER, IS

GILSON, DFR

KAWAI, NT

VLCEK, A

机构：

[1] MCGILL UNIV,DEPT CHEM,801 SHERBROOKE ST W,MONTREAL H3A 2K6,QUEBEC,CANADA

[2] J HEYROVSKY INST PHYS CHEM & ELECTROCHEM,CS-18223 PRAGUE,CZECHOSLOVAKIA

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1993年 / 24卷 / 07期

关键词：

D O I：

10.1002/jrs.1250240715

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Near-IR Fourier transform (FT) Raman spectroscopic measurements were performed at high pressures for the first time by mounting a diamond-anvil cell on the optical stage of an FT-Raman microprobe equipped with a long-range 4 x objective and by using a near-IR (Nd:YAG, 1064.1 nm) laser to excite the sample. The utility of this new pressure-tuning Raman microspectroscopic method was demonstrated by its successful application to a typical organometallic complex, Cr(CO)4(bipy)(bipy = 2.2'-bipyridyl), which decomposes under conventional visible Raman spectroscopic conditions.

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收藏

页码：471 / 473

页数：3

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