ENANTIOMER SEPARATION BY ELECTROCHROMATOGRAPHY IN OPEN TUBULAR COLUMNS COATED WITH CHIRASIL-DEX

被引：143

作者：

MAYER, S ^{[1
]}

SCHURIG, V ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST ORGAN CHEM,AUF MORGENSTELLE 18,W-7400 TUBINGEN 1,GERMANY

来源：

JOURNAL OF LIQUID CHROMATOGRAPHY | 1993年 / 16卷 / 04期

关键词：

D O I：

10.1080/10826079308020943

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The possibility of chiral interactions in a 50 mum i.d. open tubular column was created by coating the inner surface with an immobilizable dimethylpolysiloxane containing chemically bonded permethylated beta- or gamma-cyclodextrin (CHIRA-SIL-DEX). This chiral stationary phase was employed for the separation of the enantiomers of NSAIDs and small molecules by the principle of electrochromatography under various conditions.

引用

页码：915 / 931

页数：17

共 25 条

[1] ELECTRICALLY DRIVEN OPEN-TUBULAR LIQUID-CHROMATOGRAPHY [J].

BRUIN, GJM ;

TOCK, PPH ;

KRAAK, JC ;

POPPE, H .

JOURNAL OF CHROMATOGRAPHY, 1990, 517 :557-572

[2] ENANTIOSELECTIVE HYDROPHOBIC ENTANGLEMENT OF ENANTIOMERIC SOLUTES WITH CHIRAL FUNCTIONALIZED MICELLES BY ELECTROKINETIC CHROMATOGRAPHY [J].

DOBASHI, A ;

ONO, T ;

HARA, S ;

YAMAGUCHI, J .

JOURNAL OF CHROMATOGRAPHY, 1989, 480 :413-420

[3] OPTICAL RESOLUTION OF ENANTIOMERS WITH CHIRAL MIXED MICELLES BY ELECTROKINETIC CHROMATOGRAPHY [J].

DOBASHI, A ;

ONO, T ;

HARA, S ;

YAMAGUCHI, J .

ANALYTICAL CHEMISTRY, 1989, 61 (17) :1984-1986

[4] POLYMER ENCAPSULATED STATIONARY PHASES - ADVANTAGES, PROPERTIES AND SELECTIVITIES [J].

ENGELHARDT, H ;

LOW, H ;

EBERHARDT, W ;

MAUSS, M .

CHROMATOGRAPHIA, 1989, 27 (11-12) :535-543

[5] USE OF CYCLODEXTRINS FOR THE ENANTIOSELECTIVE SEPARATION OF ERGOT ALKALOIDS BY CAPILLARY ZONE ELECTROPHORESIS [J].

FANALI, S ;

FLIEGER, M ;

STEINEROVA, N ;

NARDI, A .

ELECTROPHORESIS, 1992, 13 (1-2) :39-43

[6] ELECTROKINETIC SEPARATION OF CHIRAL COMPOUNDS [J].

GASSMANN, E ;

KUO, JE ;

ZARE, RN .

SCIENCE, 1985, 230 (4727) :813-814

[7] ELECTROKINETIC RESOLUTION OF AMINO-ACID ENANTIOMERS WITH COPPER(II) ASPARTAME SUPPORT ELECTROLYTE [J].

GOZEL, P ;

GASSMANN, E ;

MICHELSEN, H ;

ZARE, RN .

ANALYTICAL CHEMISTRY, 1987, 59 (01) :44-49

[8] USE OF COMPLEXING AGENTS FOR SELECTIVE SEPARATION IN HIGH-PERFORMANCE CAPILLARY ELECTROPHORESIS - CHIRAL RESOLUTION VIA CYCLODEXTRINS INCORPORATED WITHIN POLYACRYLAMIDE-GEL COLUMNS [J].

GUTTMAN, A ;

PAULUS, A ;

COHEN, AS ;

GRINBERG, N ;

KARGER, BL .

JOURNAL OF CHROMATOGRAPHY, 1988, 448 (01) :41-53

[9] AXIAL-DISPERSION IN OPEN-TUBULAR CAPILLARY LIQUID-CHROMATOGRAPHY WITH ELECTROOSMOTIC FLOW [J].

MARTIN, M ;

GUIOCHON, G .

ANALYTICAL CHEMISTRY, 1984, 56 (04) :614-620

[10]

Mayer S., 1992, J HIGH RES CHROMATOG, V15, P129, DOI DOI 10.1002/JHRC.1240150216

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