REGIO-SELECTIVITY AND STEREO-SELECTIVITY IN THE REACTION OF METHYL 4, 5-EPOXY-2-HEXENOATE WITH METHYLCOPPER REAGENTS

被引：30

作者：

IBUKA, T

TANAKA, M

NEMOTO, H

YAMAMOTO, Y

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

[2] KYOTO UNIV,FAC PHARMACEUT SCI,KYOTO 606,JAPAN

来源：

TETRAHEDRON | 1989年 / 45卷 / 02期

关键词：

D O I：

10.1016/0040-4020(89)80071-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：435 / 442

页数：8

共 30 条

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[4] EVIDENCE FOR A REVERSIBLE D,PI-STAR-COMPLEXATION, BETA-CUPRATION SEQUENCE IN THE CONJUGATE ADDITION-REACTION OF GILMAN REAGENTS WITH ALPHA-ENONES, BETA-ENONES
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[5] D-ORBITAL STEREOELECTRONIC CONTROL OF THE STEREOCHEMISTRY OF SN2' DISPLACEMENTS BY ORGANOCUPRATE REAGENTS
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[6] SPECIFIC DIRECTING EFFECTS IN OPENING OF VICINAL HYDROXY EPOXIDES
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (02) : 394 - 396
[7] ALKYLATION OF ALLYLIC DERIVATIVES - ON THE REGIOCHEMISTRY AND STEREOCHEMISTRY OF ALKYLATION OF ALLYLIC ALCOHOLS BY THE MURAHASHI METHOD
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[8] HERR RW, 1970, J AM CHEM SOC, V92, P4919
[9] AN EFFICIENT SYNTHESIS OF CHIRAL QUATERNARY CARBON CENTERS WITH HIGH OPTICAL PURITY VIA 1,3-CHIRALITY TRANSFER
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (20) : 1596 - 1598
[10] ORGANOCOPPER-LEWIS ACID MEDIATED 1,3-CHIRALITY TRANSFER OF ACYCLIC GAMMA,DELTA-DIOXYGENATED (E)-ALPHA,BETA-ENOATES - REGIOSELECTIVE, (E)-STEREOSELECTIVE, AND DIASTEREOSELECTIVE ALPHA-ALKYLATION APPROACHING 100-PERCENT SELECTIVITY
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (23) : 7420 - 7422

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