INFLUENCE OF SUBSTRATE STRUCTURE ON COPPER(I)-ASSISTED CYANIDE SUBSTITUTION IN ARYL HALIDES

被引：16

作者：

CONNOR, JA ^{[1
]}

LEEMING, SW ^{[1
]}

PRICE, R ^{[1
]}

机构：

[1] ICI PLC,DIV ORGAN,MANCHESTER M9 3DA,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 04期

关键词：

D O I：

10.1039/p19900001127

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of various aryl halides is described: these are designed to explore the structural characteristics which are sufficient to enable copper(I)-assisted substitution of the halide by cyanide to proceed. The copper ion serves to polarise the substrate; stable co-ordination complexes are not formed. The role of various heteroatoms in the substrate is assessed and the importance of intramolecular hydrogen bonding is established.

引用

页码：1127 / 1132

页数：6

共 23 条

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