MOLECULAR GAH2CL - MATRIX INFRARED-SPECTRUM AND ABINITIO INVESTIGATIONS

被引：29

作者：

KOPPE, R ^{[1
]}

SCHNOCKEL, H ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 23期

关键词：

D O I：

10.1039/dt9920003393

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

On the basis of the matrix IR spectrum of molecular GaH2Cl, formed in a matrix reaction of H-2 and molecular GaCl, the force constants of the Ga-Cl and Ga-H bonds have been determined to be 2.38 and 2.26 mdyn angstrom-1 respectively; these results are confirmed by ab initio MP2 calculations.

引用

页码：3393 / 3395

页数：3

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