ASYMMETRIC CATALYTIC REDUCTION OF CARBONYL-COMPOUNDS USING C-2 SYMMETRICAL DIAMINES AS CHIRAL LIGANDS

被引：157

作者：

GAMEZ, P

FACHE, F

LEMAIRE, M

机构：

[1] UNIV LYON 1,ESCIL,INST RECH CATALYSE,F-69622 VILLEURBANNE,FRANCE

[2] UNIV LYON 1,ESCIL,CATALYSE & SYNTH ORGAN LAB,F-69622 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 03期

关键词：

D O I：

10.1016/0957-4166(95)00067-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The catalytic asymmetric reduction of prochiral ketones by hydride transfer using various C-2 symmetric chiral diamines as ligands and rhodium complexes is studied. Kinetic studies show an increase of the enantiomeric excess with the conversion.

引用

页码：705 / 718

页数：14

共 22 条

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