SEPARATION TECHNIQUES IN SPECIATION ANALYSIS FOR ORGANOMETALLIC SPECIES

被引：57

作者：

SZPUNARLOBINSKA, J

WITTE, C

LOBINSKI, R

ADAMS, FC

机构：

[1] Department of Chemistry, University of Antwerp (U.I.A.), Wilrijk, B-2610

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1995年 / 351卷 / 4-5期

关键词：

D O I：

10.1007/BF00322905

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A comprehensive review of the state-of-the-art of the separation of various organically-bound metals and metalloids for speciation analysis is presented. Recent developments in chromatographic (gas, liquid and supercritical fluid), electrophoretic (free-flow and gel) and fractionation techniques are discussed, followed by a survey of pertinent applications to speciation analysis for organometals and metalloids. The required sample characteristics for a given separation technique are specified and appropriate derivatization procedures are characterized. Methods applicable to the speciation of organic species of a particular element in various matrices are critically evaluated.

引用

页码：351 / 377

页数：27

共 354 条

[51] DETERMINATION OF BUTYLTIN COMPOUNDS IN RIVER SEDIMENT SAMPLES BY GAS-CHROMATOGRAPHY ATOMIC-ABSORPTION SPECTROMETRY FOLLOWING INSITU DERIVATIZATION WITH SODIUM TETRAETHYLBORATE [J].