UNEXPECTED 2-ELECTRON TRANSFER IN CYCLIC HYDRAZINES - A VOLTAMMETRIC ANALYSIS

被引：30

作者：

DIETRICH, M

HEINZE, J

FISCHER, H

NEUGEBAUER, FA

机构：

[1] UNIV FREIBURG,INST PHYS CHEM,ALBERTSTR 21,D-7800 FREIBURG,FED REP GER

[2] MAX PLANCK INST MED RES,ORGAN CHEM ABT,D-6900 HEIDELBERG 1,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1986年 / 25卷 / 11期

关键词：

ORGANIC COMPOUNDS - Electronic Properties;

D O I：

10.1002/anie.198610211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conformational changes could be shown to give rise to unusual cyclovoltammograms in the case of cyclic hydrozines. At low temperatures, these compounds formally show a two-electron transfer; in the case of the phenyl derivative the rare crossing effect is observed. All other methods of conformation analysis failed in this case.

引用

页码：1021 / 1023

页数：3

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