EXCESS PROPERTIES OF THE BINARY-LIQUID SYSTEM PROPYLENE CARBONATE + ACETONITRILE

被引：147

作者：

MOUMOUZLAS, G ^{[1
]}

PANOPOULOS, DK ^{[1
]}

RITZOULIS, G ^{[1
]}

机构：

[1] ARISTOTELIAN UNIV SALONIKA,DEPT CHEM,PHYS CHEM LAB,GR-54006 SALONIKA,GREECE

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1991年 / 36卷 / 01期

关键词：

D O I：

10.1021/je00001a006

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Dielectric constants, densities, viscosities, and refractive indices for the propylene carbonate + acetonitrile system were determined over the entire composition range of the system and at various temperatures, ranging from 25 to 45-degrees-C. Excess dielectric constants, excess volumes, excess viscosities, and excess Gibbs energies of activation of the viscous flow, as well as Kirkwood correlation factors, have been calculated and studied. Their behavior strongly suggests the existence of intermolecular interactions.

引用

页码：20 / 23

页数：4

共 14 条

[1]

[Anonymous], 1957, MOL THEORY SOLUTIONS

[2] DIELECTRIC CONSTANT OF HYDROGEN-BONDED LIQUIDS .1. CYANOACETYLENE [J].

DANNHAUSER, W ;

FLUECKIN, AF .

JOURNAL OF CHEMICAL PHYSICS, 1963, 38 (01) :69-&

[3] VISCOSITIES OF BINARY LIQUID MIXTURES [J].

FORT, RJ ;

MOORE, WR .

TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (521P) :1112-&

[4]

Frohlich H., 1958, THEORY DIELECTRICS

[5] SINGLE ION CONDUCTANCES IN NON-AQUEOUS SOLVENTS [J].

FUOSS, RM ;

HIRSCH, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (05) :1013-1017

[6] EXCESS VOLUMES AND DIELECTRIC-CONSTANTS OF BENZONITRILE + NITROBENZENE AND ACETONITRILE + NITROBENZENE SYSTEMS [J].

JANNELLI, L ;

LOPEZ, A ;

SAIELLO, S .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1983, 28 (02) :169-173

[7]

JANZ GG, 1973, NONAQUEOUS ELECTROLY, V2

[8]

Jasinski, 1967, HIGH ENERGY BATTERIE

[9] The dielectric polarization of polar liquids [J].

Kirkwood, JG .

JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (10) :911-919

[10] THERMODYNAMIC AND PHYSICAL-PROPERTIES OF BINARY-SYSTEMS INVOLVING SULFOLANE + 2-METHYLPROPIONITRILE AND SULFOLANE + 2,2-DIMETHYLPROPIONITRILE [J].

LOPEZ, A ;

JANNELLI, L ;

PANSINI, M .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1983, 28 (02) :176-179

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