TRIFLUOROPROPENE OXIDE AS A TRIFLUOROMETHYL SOURCE - PREPARATION OF OPTICALLY-ACTIVE ALCOHOLS

被引：32

作者：

TAKAHASHI, O ^{[1
]}

FURUHASHI, K ^{[1
]}

FUKUMASA, M ^{[1
]}

HIRAI, T ^{[1
]}

机构：

[1] NIPPON MIN CO LTD,MAT DEV RES LABS,TODI,SAITAMA 335,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 48期

关键词：

D O I：

10.1016/S0040-4039(00)97235-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active 3,3,3-trifluoropropene oxide(TFPO) was converted to 1,1,1-trifluoro-2-ols via Grignard type or Friedel-Crafts type reaction. The regio-selectivity of the latter reaction was discussed through an MO calculation. © 1990.

引用

页码：7031 / 7034

页数：4

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